Yes, the mune was often used defensively but according to the Nihontocraft Masahide paper, its use offensively was common practice yet rarely discussed in Western texts, and the smith would forge the blade with this application in mind.
This is the relevant section:
As for the use of the mune side of the blade in combat, this was a common tactic that was very effective in delivering a non lethal blow. Much like a "warning shot" in our frontier days or simply a mild punitive action. In many documented sword tests the mune as well as the sides of the blade were given specific and deliberate attention to make certain it could withstand the abuse of being used this way. Thus the sword is to be a complete weapon able to used in a variety of ways depending on the situation at hand.
https://www.nihontocraft.com/Suishinshi_Masahide.html